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SMPTE Journal ( Volume: 101, Issue: 5, May 1992)
[ACTIVE]

Stability of Cellulose Ester Base Photographic Film: Part III — Measurement of Film Degradation

Metadata

Publisher
SMPTE — White Plains, NY, USA
Doc Type
Journal Article
Content Type
Original Research
Abbreviated Title
SMPTE J
Volume
104, No. 5, pp. 281–291
Abstract
The degradation of safety cellulose ester base photographic film is evidenced by the release of acetic acid or other organic acids, thus the name “vinegar syndrome. ” Deterioration is also accompanied by a decrease in pH, tensile properties of the base, and wet strength of the emulsion. The acid increase can be measured by leaching the acid in 38°C water, followed by titration with sodium hydroxide. A similar procedure has been developed for use with cellulose nitrate film. The water-leaching titration method is more sensitive than pH or physical properties measurements, but suffers from the disadvantages that it requires laboratory skills and is destructive of the film. A nondestructive field test using an acid-base indicator paper has been developed.
Publication Date
1995-05-01
DOI
10.5594/J15292
ISSN
Print: 0036-1682
Link
https://doi.org/10.5594/J15292
Author(s)
P. Z. Adelstein
J. M. Reilly
D. W. Nishimura
C. J. Erbland
Details
Need to add references
Copyright
© 1995 Society of Motion Picture and Television Engineers, Inc.

Bibliographic Reference(s)

  • Archival preservation of photographic films—A perspective [Active]
  • Stability of Cellulose Ester Base Photographic Film: Part I — Laboratory Testing Procedures [Active]
  • Stability of Cellulose Ester Base Photographic Film: Part II — Practical Storage Considerations [Active]
  • The Archival Quality of Film Bases [Active]
  • Stability of Processed Cellulose Ester Photographic Films [Active]
  • Improved Safety Motion Picture Film Support [Active]
  • Stability of Processed Polyester Base Photographic Films [Active]
  • 1. Calhoun J. M. , “Storage of Nitrate Amateur Still-Camera Film Negatives,” J. Biological Photographic Assn. , 21 : 1 – 13 , Aug. 1953 . EXTERNAL
  • 11. Ram A. T. . “Archival Preservation of Photographic Films – A Perspective,” Polymer Degradation and Stability , 29 : 3 – 29 , 1990 . EXTERNAL
  • 12. Ram A. T. Masaryk-Morris S. Kopperl D. Bauer R. W. , “Simulated Aging of Processed Cellulose Triacetate Motion Picture Films,” J. Imaging Science and Technology. , 36 : 21 – 28 , Jan. 1992 . EXTERNAL
  • 14. Allen N. S. Edge M. Appleyard J. H. Jewilt T. S. Horie C. V. , “Degradation of Historic Cellulose Triacetate Cinematograph Film: Influence of Various Film Parameters and Prediction of Archival Life,” J. Photographic Science , 36 : 194 – 198 , 1988 . EXTERNAL
  • 15. Edge M. Allen N. S. Jewitt T. S. Appleyard J. H. Horie C. V. , “The Deterioration Characteristics of Archival Cellulose Triacetate Base Cinematograph Film,” ibid . pp. 199 – 203 . EXTERNAL
  • 16. Edge M. Allen N. S. Jewitt T. S. Horie C.V. , “Fundamental Aspects of the Degradation of Cellulose Triacetate Base Cinematograph Film,” Polymer Degradation and Stability. , 25 : 345 – 362 , 1989 . EXTERNAL
  • 17. Edge M. Allen N. S. Jewitt T. S. , “The Inhibition of Oxidative and Hydrolytic Degradation Pathways in Archival Cellulose Triacetate Base Cinematograph Films,” Polymer Degradation and Stability. , 29 : 31 – 48 , 1990 . EXTERNAL
  • 18. Allen N. S. Edge M. Jewitt T. S. Horie C. V. , “Initiation of the Degradation of Cellulose Triacetate Base Motion Picture Film.” J. Photographic Science , 38 : 54 – 59 . 1990 . EXTERNAL
  • 19. Allen N. S. Edge M. Jewitt T. S. Horie C. V. , “Degradation and Stabilization of Cellulose Triacetate Base Motion Picture Film,” J. Imaging Science and Technology , 36 : 4 – 12 . Jan./Feb. 1992 . EXTERNAL
  • 2. Calhoun J. M. , “Old Nitrate Films are Dangerous.” Intl. Projectionist . 8 – 18 , May 1962 . EXTERNAL
  • 21. Adelstein P. Z. Reilly J. M. Nishimura D. W. Erbland C. J. , “Stability of Cellulose Ester Base Photographic Film: Part II — Practical Storage Considerations,” ibid . pp. 347 – 353 . EXTERNAL
  • 22. American National Standard for Imaging Media (Film) - Silver-Gelatin Type — Specification for Stability , IT9 .1– 1992 . EXTERNAL
  • 23. Miles C. E. , “Wood Coatings for Display and Storage Cases,” Studies in Conservation . 31 : 114 . 1986 . EXTERNAL
  • 24. Adelstein P. Z. Reilly J. M. Nishimura D. W. Erbland C. J. , “Stability of Cellulose Ester Base Photographic Film: Part V - Recent Findings on Film Stability.” to appear in future SMPTE. J. EXTERNAL
  • 25. Adelstein P. Z. Reilly J. M. Nishimura D. W. Erbland C. J. , “Stability of Cellulose Ester Base Photographic Film: Part IV - Behavior of Nitrate Base Films.” to appear in future SMPTE J. EXTERNAL
  • 3. Calhoun J. M. , “Technology of New Film Bases,” Perspective , 2 . 1960 . EXTERNAL
  • 4. Adelstein P. Z. , “From Metal to Polyester: History of Picture-Taking Support,” Pioneers of Photography , ed. by Ostroff E. . pp. 30 – 36 . Society for Imaging Science and technology, 1987 . EXTERNAL
  • 6. Adelstein P. Z. McCrea J. L. . “Permanence of Processed ‘Estar’ Polyester Base Photographic Films,” Photographic Science and Engineers , 9 : 305 – 3 13, Sept./Oct. 1965 . EXTERNAL
  • 7. Adelstein P. Z. , “Preservation of Microfilm.” J. Micrographics. , 11 : 333 – 337 , July/Aug. 1978 . EXTERNAL
  • 8. Adelstein P. Z. McCrea J. L. , “Stability of Processed Polyester Base Photographic Films,” J. Applied Photographic Engineers. , 7 : 160 – 167 , Dec. 1981 . EXTERNAL
  • 9. Horvath D. G. . “The Acetate Negative Survey.” Ekstrom Library. Univ. of Louisville , Feb. 1987 . EXTERNAL
  • Improved Safety Motion Picture Film Support EXTERNAL
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P. Z. Adelstein, J. M. Reilly, D. W. Nishimura, and C. J. Erbland; Stability of Cellulose Ester Base Photographic Film: Part III — Measurement of Film Degradation, SMPTE Journal ( Volume: 101, Issue: 5, May 1992); SMPTE, 1995. Available at https://doi.org/10.5594/J15292
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P. Z. Adelstein, J. M. Reilly, D. W. Nishimura, and C. J. Erbland; Stability of Cellulose Ester Base Photographic Film: Part III — Measurement of Film Degradation, SMPTE Journal ( Volume: 101, Issue: 5, May 1992); SMPTE, 1995. Available at https://doi.org/10.5594/J15292

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P. Z. Adelstein, J. M. Reilly, D. W. Nishimura, and C. J. Erbland; Stability of Cellulose Ester Base Photographic Film: Part III — Measurement of Film Degradation, SMPTE Journal ( Volume: 101, Issue: 5, May 1992); SMPTE, 1995. Available at https://doi.org/10.5594/J15292
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<span class="citation">P. Z. Adelstein, J. M. Reilly, D. W. Nishimura, and C. J. Erbland; <cite>Stability of Cellulose Ester Base Photographic Film: Part III — Measurement of Film Degradation</cite>, SMPTE Journal ( Volume: 101, Issue: 5, May 1992); SMPTE, 1995. Available at <a href="https://doi.org/10.5594/J15292" target="_blank" rel="noopener">https://doi.org/10.5594/J15292</a></span>

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P. Z. Adelstein, J. M. Reilly, D. W. Nishimura, and C. J. Erbland; Stability of Cellulose Ester Base Photographic Film: Part III — Measurement of Film Degradation, SMPTE Journal ( Volume: 101, Issue: 5, May 1992); SMPTE, 1995
doi: 10.5594/J15292
url: https://doi.org/10.5594/J15292
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P. Z. Adelstein, J. M. Reilly, D. W. Nishimura, and C. J. Erbland; <cite id="bib-10-5594-j15292">Stability of Cellulose Ester Base Photographic Film: Part III — Measurement of Film Degradation</cite>, SMPTE Journal ( Volume: 101, Issue: 5, May 1992); SMPTE, 1995
<span class="doi">10.5594/J15292</span>
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