Stability of Cellulose Ester Base Photographic Film: Part III — Measurement of Film Degradation
Metadata
- Publisher
- SMPTE — White Plains, NY, USA
- Doc Type
- Journal Article
- Content Type
- Original Research
- Abbreviated Title
- SMPTE J
- Volume
- 104, No. 5, pp. 281–291
- Abstract
- The degradation of safety cellulose ester base photographic film is evidenced by the release of acetic acid or other organic acids, thus the name “vinegar syndrome. ” Deterioration is also accompanied by a decrease in pH, tensile properties of the base, and wet strength of the emulsion. The acid increase can be measured by leaching the acid in 38°C water, followed by titration with sodium hydroxide. A similar procedure has been developed for use with cellulose nitrate film. The water-leaching titration method is more sensitive than pH or physical properties measurements, but suffers from the disadvantages that it requires laboratory skills and is destructive of the film. A nondestructive field test using an acid-base indicator paper has been developed.
- Publication Date
- 1995-05-01
- DOI
10.5594/J15292- ISSN
- Print:
0036-1682 - Link
- https://doi.org/10.5594/J15292
- Author(s)
- P. Z. AdelsteinJ. M. ReillyD. W. NishimuraC. J. Erbland
- Details
- Need to add references
- Copyright
- © 1995 Society of Motion Picture and Television Engineers, Inc.
Bibliographic Reference(s)
- Archival preservation of photographic films—A perspective [Active]
- Stability of Cellulose Ester Base Photographic Film: Part I — Laboratory Testing Procedures [Active]
- Stability of Cellulose Ester Base Photographic Film: Part II — Practical Storage Considerations [Active]
- The Archival Quality of Film Bases [Active]
- Stability of Processed Cellulose Ester Photographic Films [Active]
- Improved Safety Motion Picture Film Support [Active]
- Stability of Processed Polyester Base Photographic Films [Active]
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- 12. Ram A. T. Masaryk-Morris S. Kopperl D. Bauer R. W. , “Simulated Aging of Processed Cellulose Triacetate Motion Picture Films,” J. Imaging Science and Technology. , 36 : 21 – 28 , Jan. 1992 . EXTERNAL
- 14. Allen N. S. Edge M. Appleyard J. H. Jewilt T. S. Horie C. V. , “Degradation of Historic Cellulose Triacetate Cinematograph Film: Influence of Various Film Parameters and Prediction of Archival Life,” J. Photographic Science , 36 : 194 – 198 , 1988 . EXTERNAL
- 15. Edge M. Allen N. S. Jewitt T. S. Appleyard J. H. Horie C. V. , “The Deterioration Characteristics of Archival Cellulose Triacetate Base Cinematograph Film,” ibid . pp. 199 – 203 . EXTERNAL
- 16. Edge M. Allen N. S. Jewitt T. S. Horie C.V. , “Fundamental Aspects of the Degradation of Cellulose Triacetate Base Cinematograph Film,” Polymer Degradation and Stability. , 25 : 345 – 362 , 1989 . EXTERNAL
- 17. Edge M. Allen N. S. Jewitt T. S. , “The Inhibition of Oxidative and Hydrolytic Degradation Pathways in Archival Cellulose Triacetate Base Cinematograph Films,” Polymer Degradation and Stability. , 29 : 31 – 48 , 1990 . EXTERNAL
- 18. Allen N. S. Edge M. Jewitt T. S. Horie C. V. , “Initiation of the Degradation of Cellulose Triacetate Base Motion Picture Film.” J. Photographic Science , 38 : 54 – 59 . 1990 . EXTERNAL
- 19. Allen N. S. Edge M. Jewitt T. S. Horie C. V. , “Degradation and Stabilization of Cellulose Triacetate Base Motion Picture Film,” J. Imaging Science and Technology , 36 : 4 – 12 . Jan./Feb. 1992 . EXTERNAL
- 2. Calhoun J. M. , “Old Nitrate Films are Dangerous.” Intl. Projectionist . 8 – 18 , May 1962 . EXTERNAL
- 21. Adelstein P. Z. Reilly J. M. Nishimura D. W. Erbland C. J. , “Stability of Cellulose Ester Base Photographic Film: Part II — Practical Storage Considerations,” ibid . pp. 347 – 353 . EXTERNAL
- 22. American National Standard for Imaging Media (Film) - Silver-Gelatin Type — Specification for Stability , IT9 .1– 1992 . EXTERNAL
- 23. Miles C. E. , “Wood Coatings for Display and Storage Cases,” Studies in Conservation . 31 : 114 . 1986 . EXTERNAL
- 24. Adelstein P. Z. Reilly J. M. Nishimura D. W. Erbland C. J. , “Stability of Cellulose Ester Base Photographic Film: Part V - Recent Findings on Film Stability.” to appear in future SMPTE. J. EXTERNAL
- 25. Adelstein P. Z. Reilly J. M. Nishimura D. W. Erbland C. J. , “Stability of Cellulose Ester Base Photographic Film: Part IV - Behavior of Nitrate Base Films.” to appear in future SMPTE J. EXTERNAL
- 3. Calhoun J. M. , “Technology of New Film Bases,” Perspective , 2 . 1960 . EXTERNAL
- 4. Adelstein P. Z. , “From Metal to Polyester: History of Picture-Taking Support,” Pioneers of Photography , ed. by Ostroff E. . pp. 30 – 36 . Society for Imaging Science and technology, 1987 . EXTERNAL
- 6. Adelstein P. Z. McCrea J. L. . “Permanence of Processed ‘Estar’ Polyester Base Photographic Films,” Photographic Science and Engineers , 9 : 305 – 3 13, Sept./Oct. 1965 . EXTERNAL
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- 9. Horvath D. G. . “The Acetate Negative Survey.” Ekstrom Library. Univ. of Louisville , Feb. 1987 . EXTERNAL
- Improved Safety Motion Picture Film Support EXTERNAL
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P. Z. Adelstein, J. M. Reilly, D. W. Nishimura, and C. J. Erbland; Stability of Cellulose Ester Base Photographic Film: Part III — Measurement of Film Degradation, SMPTE Journal ( Volume: 101, Issue: 5, May 1992); SMPTE, 1995. Available at https://doi.org/10.5594/J15292
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P. Z. Adelstein, J. M. Reilly, D. W. Nishimura, and C. J. Erbland; Stability of Cellulose Ester Base Photographic Film: Part III — Measurement of Film Degradation, SMPTE Journal ( Volume: 101, Issue: 5, May 1992); SMPTE, 1995. Available at https://doi.org/10.5594/J15292
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P. Z. Adelstein, J. M. Reilly, D. W. Nishimura, and C. J. Erbland; Stability of Cellulose Ester Base Photographic Film: Part III — Measurement of Film Degradation, SMPTE Journal ( Volume: 101, Issue: 5, May 1992); SMPTE, 1995. Available at https://doi.org/10.5594/J15292
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<span class="citation">P. Z. Adelstein, J. M. Reilly, D. W. Nishimura, and C. J. Erbland; <cite>Stability of Cellulose Ester Base Photographic Film: Part III — Measurement of Film Degradation</cite>, SMPTE Journal ( Volume: 101, Issue: 5, May 1992); SMPTE, 1995. Available at <a href="https://doi.org/10.5594/J15292" target="_blank" rel="noopener">https://doi.org/10.5594/J15292</a></span>
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P. Z. Adelstein, J. M. Reilly, D. W. Nishimura, and C. J. Erbland; Stability of Cellulose Ester Base Photographic Film: Part III — Measurement of Film Degradation, SMPTE Journal ( Volume: 101, Issue: 5, May 1992); SMPTE, 1995
doi: 10.5594/J15292
url: https://doi.org/10.5594/J15292
doi: 10.5594/J15292
url: https://doi.org/10.5594/J15292
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<li> P. Z. Adelstein, J. M. Reilly, D. W. Nishimura, and C. J. Erbland; <cite id="bib-10-5594-j15292">Stability of Cellulose Ester Base Photographic Film: Part III — Measurement of Film Degradation</cite>, SMPTE Journal ( Volume: 101, Issue: 5, May 1992); SMPTE, 1995 <span class="doi">10.5594/J15292</span> </li>
Referenced By
- Ventilated Film Cans—Their Effect on the Diffusion of Decomposition By-products from Motion Picture Film [Active]
- Stability of Cellulose Ester Base Photographic Film: Part IV—Behavior of Nitrate Base Film [Active]
- Stability of Cellulose Ester Base Photographic Film: Part V—Recent Findings [Active]
- SMPTE RP 131:2002 [Active, Stabilized]