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SMPTE Journal ( Volume: 97, Issue: 6, June 1988)
[ACTIVE]

Stability of Processed Cellulose Ester Photographic Films

Metadata

Publisher
SMPTE — White Plains, NY, USA
Doc Type
Journal Article
Content Type
Original Research
Abbreviated Title
J SMPTE
Volume
97, No. 6, pp. 474–483
Abstract
The chemical stability of cellulose ester photographic film support is extremely important to archival keeping behavior. A 1981 study predicted that cellulose triacetate support films would have acceptable physical properties for at least 300 years under recommended storage conditions. This study on the total film, however, masked some of the degradation reactions resulting from the amphoteric nature of the gelatin emulsions. The effects of commonly used cellulose nitrate subbing material and triphenyl phosphate flame-retardant plasticizer on nonsensitized cellulose triacetate supports are now reported. These nonsensitized supports, after high-temperature incubations, follow a similar Arrhenius relationship, indicating that the presence of the sub and the plasticizer, at the concentrations commonly used with Kodak cellulose ester films, does not affect their archival keeping behavior. Recommendations for proper storage to prolong the useful life of these processed films are outlined.
Publication Date
1988-06-01
DOI
10.5594/J02945
ISSN
Print: 0036-1682
Link
https://doi.org/10.5594/J02945
Author(s)
A. Tulsi RamEastman Kodak Co., Rochester, NY 14650.
James L. McCreaEastman Kodak Co., Rochester, NY 14650.
Details
Need to add references
Copyright
© 1988 Society of Motion Picture and Television Engineers, Inc.

Bibliographic Reference(s)

  • Improved Safety Motion Picture Film Support [Active]
  • 1. Ott E. Spurlin H. M. , “Cellulose and Cellulose Derivatives,” High Polymers , vol. V. , 2nd ed. (Parts I, II, III), Interscience Publishers : New York, NY , 1954 . EXTERNAL
  • 10. Wilson W. K. Forshee B. W. , “Degradation of Cellulose Acetate Films,” J. Soc. Plastics Eng. , 15 : 146 – 156 , 1959 . EXTERNAL
  • 11. Neblette C. B. , Photography: Its Materials and Processes , Van Nostrand Reinhold Co. : New York , 1962 , pp. 161 – 179 . EXTERNAL
  • 13. Hendrix J. E. . “Pyrolysis and Combustion of Cellulose. I. Effects of Triphenyl Phosphate in the Presence of Nitrogenous Bases,” J. Appl. Polymer Science , 14 :1701–1723, 1970 . EXTERNAL
  • 14. Pollakowski G. , “How Safe Is Safety Film,” (German), Bild und Ton , 40 : 90 – 91 , 1987 . EXTERNAL
  • 15. Hill J. R. Weber C.G. , “Stability of Motion-Picture Films as Determined by Accelerated Aging,” Research Paper RP 950, J. Res. Nat. Bur. of Standards , 17 : 871 – 881 , 1936 . EXTERNAL
  • 16. Adelstein P. Z. McCrea J. L. , “Stability of Processed Polysler Base Photographic Films,” J. Appl. Photogr. Eng. , 7 : 160 – 167 , 1981 . EXTERNAL
  • 17. Adelstein P. Z. McCrea J. L. , “Permanence of Processed Estar Polyester Base Photographic Films,” Photogr. Sci. Eng. , 9 : 305 – 313 , 1965 . EXTERNAL
  • 18. Lee W. E. Bard C. C. , “The Stability of Kodak Professional Motion Picture Film Bases,” presented at 128th SMPTE Technical Conference, New York, NY, Oct. 1986 . EXTERNAL
  • 19. Richter G. A. Wells F. L. , “Influence of Moisture in Accelerated Aging of Cellulose,” J. T APPL , 39 : 603 – 608 , 1956 . EXTERNAL
  • 2. Nevell T. P. Zeronian S. H. , “Cellulose Chemistry and Its Applications,” Ellis Horwood Ltd. Div. John Wiley & Sons : New York , 1985 . EXTERNAL
  • 20. “Method of Testing Cellulose Acetate,” D871 – 72 , American Society for Testing and Materials , Philadelphia, PA . EXTERNAL
  • 21. “Method of Test for Tensile Properties of Thin Plastic Sheeting,” D882 – 75b , American Society for Testing and Materials , Philadelphia, PA. EXTERNAL
  • 22. Adelstein P. Z. McCrea J. L. , “Dark Image-Stability of Diazo Films,” J. Appl. Photogr. Eng. , 3 : 173 – 178 , 1977 . EXTERNAL
  • 23. Bard C. C. . “Predicting Long-Term Dark Keeping Storage Dye Stability Characteristics of Color Photographic Products from Short-Term Tests,” J. Appl. Photogr. Eng. , 6 :42–45, 1980 . EXTERNAL
  • 24. Hiller L. A. , “The Reaction of Cellulose Acetate with Acetic Acid and Water,” J. Polymer Sci. , 10 : 385 – 423 , 1953 . EXTERNAL
  • 25. The Book of Film Care , publication H-23, Eastman Kodak Co. , Rochester, NY , 1983 . EXTERNAL
  • 26. Preservation of Photographs , publication F-30, Eastman Kodak Co. , Rochester, NY , 1979 . EXTERNAL
  • 3. Scotney A. , “Thermal Degradation of Cellulose Acetate, Parts I, II, and III,” European Polymer J. , 8 : 163 – 193 , 1971 . EXTERNAL
  • 4. Madorsky S. L. , Thermal Degradation of Organic Polymers , Interscience Publishers : New York , 1964 , pp. 238 – 261 . EXTERNAL
  • 5. Evans E. F. McBurney L. F. , “Heat Stability of Cellulose Acetate,” Ind. and Eng. Chem. , 41 : 1260 – 1264 , 1949 . EXTERNAL
  • 6. Madorsky S. L. Hart V. E. Straus S. , “Pyrolysis of Cellulose in Vacuum,” J. Res. Nat. Bur. of Standards , 56 : 343 – 354 , 1956 . EXTERNAL
  • 7. Madorsky S. L. Hart V. E. Straus S. , “Thermal Degradation of Cellulosic Materials,” J. Res. Nat. Bur. of Standards , 60 : 343 – 349 , 1958 . EXTERNAL
  • 8. DeCroes G. C. Tamblyn J. W. , “Protection of Cellulose Esters Against Breakdown by Heat and Light,” Mod. Plastics , 29 : 127 – 136 , 185 – 189 , 1952 . EXTERNAL
  • 9. Freiman A. A. Scherbakova V. A. , “Thermal and Thermohydrolytic Decomposition of Cellulose Acetate and Films Made Thereof,” Zhur. Priklad. Khim. , 24 : 853 – 859 , 1951 . EXTERNAL
  • Improved Safety Motion Picture Film Support EXTERNAL
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A. Tulsi Ram and James L. McCrea; Stability of Processed Cellulose Ester Photographic Films, SMPTE Journal ( Volume: 97, Issue: 6, June 1988); SMPTE, 1988. Available at https://doi.org/10.5594/J02945
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A. Tulsi Ram and James L. McCrea; Stability of Processed Cellulose Ester Photographic Films, SMPTE Journal ( Volume: 97, Issue: 6, June 1988); SMPTE, 1988. Available at https://doi.org/10.5594/J02945

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A. Tulsi Ram and James L. McCrea; Stability of Processed Cellulose Ester Photographic Films, SMPTE Journal ( Volume: 97, Issue: 6, June 1988); SMPTE, 1988. Available at https://doi.org/10.5594/J02945
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<span class="citation">A. Tulsi Ram and James L. McCrea; <cite>Stability of Processed Cellulose Ester Photographic Films</cite>, SMPTE Journal ( Volume: 97, Issue: 6, June 1988); SMPTE, 1988. Available at <a href="https://doi.org/10.5594/J02945" target="_blank" rel="noopener">https://doi.org/10.5594/J02945</a></span>

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A. Tulsi Ram and James L. McCrea; Stability of Processed Cellulose Ester Photographic Films, SMPTE Journal ( Volume: 97, Issue: 6, June 1988); SMPTE, 1988
doi: 10.5594/J02945
url: https://doi.org/10.5594/J02945
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A. Tulsi Ram and James L. McCrea; <cite id="bib-10-5594-j02945">Stability of Processed Cellulose Ester Photographic Films</cite>, SMPTE Journal ( Volume: 97, Issue: 6, June 1988); SMPTE, 1988
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