A Bleach System for Color Positive and Negative Film That Reduces Waste Treatment Requirements

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Publisher: SMPTE — White Plains, NY, USA
Doc Type: Journal Article
Content Type: Original Research
Abbreviated Title: J SMPTE
Volume: 87, No. 2, pp. 84–88
Abstract: Federal, state and municipal regulations on the disposal of industrial waste water have stimulated much photographic industry activity where chemical and mechanical methods must be devised to comply with the regulations. Several systems are in use for treating the major problems of photographic waste water. The bleach solution is one of the most troublesome materials to treat because of the presence of heavy metals or cyanides. The concentration of these substances must be reduced to a level of 0.1 ppm. Work is described that has been done to develop and test a bleach formula that contains no chromium, iron or cyanides. A copper halide bleach was found to be attractive because under current regulations permissible levels for copper are 15 times greater than for cyanide or hexavalent chromium. Either cupric bromide or cupric chloride could be used, and the latter was selected for testing because it has a cost advantage. A 21-g/I concentration was found to give bleaching times equivalent to SR27. The replenishing rate is 654 liters per million feet of 35mm Eastman color positive film (5381).
Publication Date: 1978-02-01
DOI: 10.5594/J17435
ISSN: Print: 0036-1682
Link: https://doi.org/10.5594/J17435
Author(s): C. Russell DupreeColor Film Corp., 777 Washington Blvd., Stamford, CT 06901
Copyright: © 1978 Society of Motion Picture and Television Engineers, Inc.

Bibliographic Reference(s)

Treatment of Photographic Ferrocyanide-Type Bleach Solutions for Reuse and Disposal [Active]
Spring-Loaded Wiper-Blade Squeegees [Active]
1. Bober T. W. Dogan T. J. , “The Regeneration of Ferrocyanide Bleach Using Ozone,” Image Technol. , 14 : 13 – 24 , June-July 1972 . EXTERNAL
4. Garrison R. C. , Air Force Weapons Laboratory Report, AFWL-TR-73–212, Feb. 1971 . EXTERNAL
5. Cooley A. C. , J. Appl. Photo. Eng. , 2 : 61 – 74 , Spring 1976 . EXTERNAL
6. Avery N. L. Fries W. , Ind. Eng. Chem., Prod. R & D , 14 : 102 , June 1975 . EXTERNAL
7. Näsänen Ann. Acad. Sc. Fennicae , A59 No. 7 , 15 March 1943 . EXTERNAL

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C. Russell Dupree; A Bleach System for Color Positive and Negative Film That Reduces Waste Treatment Requirements, SMPTE Journal ( Volume: 87, Issue: 2, February 1978); SMPTE, 1978. Available at https://doi.org/10.5594/J17435

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C. Russell Dupree; A Bleach System for Color Positive and Negative Film That Reduces Waste Treatment Requirements, SMPTE Journal ( Volume: 87, Issue: 2, February 1978); SMPTE, 1978. Available at https://doi.org/10.5594/J17435

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<span class="citation">C. Russell Dupree; <cite>A Bleach System for Color Positive and Negative Film That Reduces Waste Treatment Requirements</cite>, SMPTE Journal ( Volume: 87, Issue: 2, February 1978); SMPTE, 1978. Available at <a href="https://doi.org/10.5594/J17435" target="_blank" rel="noopener">https://doi.org/10.5594/J17435</a></span>

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C. Russell Dupree; <cite id="bib-10-5594-j17435">A Bleach System for Color Positive and Negative Film That Reduces Waste Treatment Requirements</cite>, SMPTE Journal ( Volume: 87, Issue: 2, February 1978); SMPTE, 1978
<span class="doi">10.5594/J17435</span>
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