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Journal of the Society of Motion Picture Engineers ( Volume: 38, Issue: 2, February 1942)
[ACTIVE]

Iodide Analysis in an Mq Developer

Metadata

Publisher
SMPTE — White Plains, NY, USA
Doc Type
Journal Article
Content Type
Original Research
Abbreviated Title
J SMPE
Volume
38, No. 2, pp. 180–187
Abstract
A method is described for the analysis of iodide in a developer involving precipitation of the halide with silver nitrate and oxidation of the iodide while it is in the form of solid silver iodide to iodate with chlorine water. The iodate is then determined polarographically. Quantities of iodide from 2.5 to 10 milligrams of potassium iodide were analyzed with an accuracy of 2–4 per cent. Thiocyanate in the developer interferes but it can be removed by boiling with strong sulfuric acid before precipitation. Using this method of analysis it was shown that an equilibrium amount of iodide is obtained in a developer. Curves are given showing the attainment of equilibrium for development of Eastman panchromatic negative motion picture film, in Kodak D-76, and in Kodak D-16 developers, and Eastman positive motion picture film in Kodak D-16. The equilibrium value depends on the emulsion, the developer, the developed density, and perhaps other variables which will be investigated more thoroughly.
Publication Date
1942-02-01
DOI
10.5594/J09929
ISSN
Print: 0097-5834
Link
https://doi.org/10.5594/J09929
Author(s)
R. M. EvansEastman Kodak Company, Rochester, N. Y.
W. T. HansonEastman Kodak Company, Rochester, N. Y.
P. K. GlasoeEastman Kodak Company, Rochester, N. Y.
Copyright
© 1942 Society of Motion Picture and Television Engineers, Inc.

Bibliographic Reference(s)

  • 1 Evans R. M. Hanson W. T. Jr. : “Chemical Analysis of an MQ Developer,” J. Soc. Mot. Pict. Eng. , XXXII (March, 1939 ), p. 307 . EXTERNAL
  • 2 Baumbach H. L. : “The Chemical Analysis of Metol, Hydroquinone, and Bromide in a Photographic Developer,” J. Soc. Mot. Pict. Eng. , XXXIII (Nov., 1939 ), p. 517 . EXTERNAL
  • 3 Atkinson R. B. Shaner V. C. : “Chemical Analysis of Photographic Developers and Fixing Baths,” J. Soc. Mot. Pict. Eng. , XXXIV (May, 1940 ), p. 485 . EXTERNAL
  • 4 Rylich A. : “Polarographic Studies with the Dropping Mercury Cathode: Electroreduction and Estimation of Bromates and Iodates,” Collections Czech. Chem. Comm. , 7 , ( 1935 ), p. 288 . EXTERNAL
  • 5 Kolthoff I. M. Lingane J. J. : “The Fundamental Principles and Applications of Electrolysis with the Dropping Mercury Electrode and Heyrovsky's Polarographic Method of Chemical Analysis,” Chem. Rev. , 24 , (Feb., 1939 ), p. 1 . EXTERNAL
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R. M. Evans, W. T. Hanson, and P. K. Glasoe; Iodide Analysis in an Mq Developer, Journal of the Society of Motion Picture Engineers ( Volume: 38, Issue: 2, February 1942); SMPTE, 1942. Available at https://doi.org/10.5594/J09929
Snippet:
R. M. Evans, W. T. Hanson, and P. K. Glasoe; Iodide Analysis in an Mq Developer, Journal of the Society of Motion Picture Engineers ( Volume: 38, Issue: 2, February 1942); SMPTE, 1942. Available at https://doi.org/10.5594/J09929

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R. M. Evans, W. T. Hanson, and P. K. Glasoe; Iodide Analysis in an Mq Developer, Journal of the Society of Motion Picture Engineers ( Volume: 38, Issue: 2, February 1942); SMPTE, 1942. Available at https://doi.org/10.5594/J09929
Snippet:
<span class="citation">R. M. Evans, W. T. Hanson, and P. K. Glasoe; <cite>Iodide Analysis in an Mq Developer</cite>, Journal of the Society of Motion Picture Engineers ( Volume: 38, Issue: 2, February 1942); SMPTE, 1942. Available at <a href="https://doi.org/10.5594/J09929" target="_blank" rel="noopener">https://doi.org/10.5594/J09929</a></span>

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R. M. Evans, W. T. Hanson, and P. K. Glasoe; Iodide Analysis in an Mq Developer, Journal of the Society of Motion Picture Engineers ( Volume: 38, Issue: 2, February 1942); SMPTE, 1942
doi: 10.5594/J09929
url: https://doi.org/10.5594/J09929
Snippet:
<li>
R. M. Evans, W. T. Hanson, and P. K. Glasoe; <cite id="bib-10-5594-j09929">Iodide Analysis in an Mq Developer</cite>, Journal of the Society of Motion Picture Engineers ( Volume: 38, Issue: 2, February 1942); SMPTE, 1942
<span class="doi">10.5594/J09929</span>
</li>