Studies on a Copper-Toned Planographic Dye Transfer Matrix—Part I

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Publisher: SMPTE — White Plains, NY, USA
Doc Type: Journal Article
Content Type: Original Research
Abbreviated Title: J SMPTE
Volume: 74, No. 11, pp. 989–994
Abstract: The advantages of a planographic dye transfer matrix over a conventional relief matrix include improved image sharpness and reduced image graininess in the resulting print, and greater flexibility in construction of the raw stock and its use by avoiding the requirement for exposure through the film base. A plano-graphic matrix may be prepared by reversal processing of the stock after exposure, followed by toning the reversal silver image. The dye resist formed by copper toning of this image is believed to be a semipermeable membrane of copper ferrocyanide which forms at the interface between the silver-gelatin “non-image” and the gelatin “image” or at the surface of the film. A mechanism is proposed for the formation of this membrane and experimental evidence in support of this mechanism is presented. The importance of such factors as Cu/Fe ratio, pH, properties of the stabilizing ligand, and nature of the anion in the toning solution is discussed.
Publication Date: 1965-11-01
DOI: 10.5594/J05974
ISSN: Print: 0361-4573
Link: https://doi.org/10.5594/J05974
Author(s): Philip N. JamesTechnicolor Corp. of America, 2800 W. Olive Ave., Burbank, Calif. 91505
Copyright: © 1965 Society of Motion Picture and Television Engineers, Inc.

Bibliographic Reference(s)

1. Whitmore K. E. Williams J. , U.S. Pat. 2,940,849. EXTERNAL
2. Tull A. G. , U.S. Pat. 2,930,691. EXTERNAL
3. Rigamonti R. , Gazz. chim. ital. , 68 : 809 ( 1938 ) and earlier papers; H. B. Weiser, W. O. Milligan and J. B. Bates, J. Phys. Chem., 42: 945 (1938); N. V. Sidgwick, The Chemical Elements and Their Compounds, Oxford University Press, London, 1950, p. 1338 . EXTERNAL
4. Andreas J. M. , private communication. EXTERNAL

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Philip N. James; Studies on a Copper-Toned Planographic Dye Transfer Matrix—Part I, Journal of the SMPTE ( Volume: 74, Issue: 11, November 1965); SMPTE, 1965. Available at https://doi.org/10.5594/J05974

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Philip N. James; Studies on a Copper-Toned Planographic Dye Transfer Matrix—Part I, Journal of the SMPTE ( Volume: 74, Issue: 11, November 1965); SMPTE, 1965. Available at https://doi.org/10.5594/J05974

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<span class="citation">Philip N. James; <cite>Studies on a Copper-Toned Planographic Dye Transfer Matrix—Part I</cite>, Journal of the SMPTE ( Volume: 74, Issue: 11, November 1965); SMPTE, 1965. Available at <a href="https://doi.org/10.5594/J05974" target="_blank" rel="noopener">https://doi.org/10.5594/J05974</a></span>

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Philip N. James; Studies on a Copper-Toned Planographic Dye Transfer Matrix—Part I, Journal of the SMPTE ( Volume: 74, Issue: 11, November 1965); SMPTE, 1965
doi: 10.5594/J05974
url: https://doi.org/10.5594/J05974

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<li>
Philip N. James; <cite id="bib-10-5594-j05974">Studies on a Copper-Toned Planographic Dye Transfer Matrix—Part I</cite>, Journal of the SMPTE ( Volume: 74, Issue: 11, November 1965); SMPTE, 1965
<span class="doi">10.5594/J05974</span>
</li>

Referenced By

Progress Committee Report for 1965 [Active]